Physician
General Surgery
Dr. Robert D. Bach, MD
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Robert Bach works in the field of General Surgery. He has 1 awards "Fellow (FACS)". Doctor Robert D. Bach, MD has written publications. He has 23 publications published with PubMed. The lastest publication is: 'Mechanistic Aspects Regarding the Elimination of H2O2 from C(4a)-Hydroperoxyflavin. The Role of a Proton Shuttle Required for H2O2 Elimination.' He is registered with Medicare and accepts Medicare payments.
Publications
- Mechanistic Aspects Regarding the Elimination of H2O2 from C(4a)-Hydroperoxyflavin. The Role of a Proton Shuttle Required for H2O2 Elimination.
- The Role of the Somersault Rearrangement in the Oxidation Step for Flavin Monooxygenases (FMO). A Comparison between FMO and Conventional Xenobiotic Oxidation with Hyd...
- The rate-limiting step in P450 hydroxylation of hydrocarbons a direct comparison of the "somersault" versus the "consensus" mechanism involving compound I.
- Transient inverted metastable iron hydroperoxides in fenton chemistry. A nonenzymatic model for cytochrome p450 hydroxylation.
- Ring strain energy in the cyclooctyl system. The effect of strain energy on [3 + 2] cycloaddition reactions with azides.
- The Curtius rearrangement of cyclopropyl and cyclopropenoyl azides. A combined theoretical and experimental mechanistic study.
- Mechanism of thiolate-disulfide interchange reactions in biochemistry.
- Mechanism of SN2 disulfide bond cleavage by phosphorus nucleophiles. Implications for biochemical disulfide reducing agents.
- The effect of carbonyl substitution on the strain energy of small ring compounds and their six-member ring reference compounds.
- The "somersault" mechanism for the p-450 hydroxylation of hydrocarbons. The intervention of transient inverted metastable hydroperoxides.
- Chemical behavior of the biradicaloid (HO...ONO) singlet states of peroxynitrous acid. The oxidation of hydrocarbons, sulfides, and selenides.
- Computational studies of nucleophilic substitution at carbonyl carbon: the S(N)2 mechanism versus the tetrahedral intermediate in organic synthesis.
- A reactivity/affinity switch for parallel kinetic resolution: alpha-amino acid quasienantiomers and the resolution of cyclopropene carboxylic acids.
- Strain energy of small ring hydrocarbons. Influence of C-h bond dissociation energies.
- Model studies on p-hydroxybenzoate hydroxylase. The catalytic role of Arg-214 and Tyr-201 in the hydroxylation step.
- Theoretical analysis of peroxynitrous acid: characterization of its elusive biradicaloid (HO...ONO) singlet states.
- Relative reactivity of peracids versus dioxiranes (DMDO and TFDO) in the epoxidation of alkenes. A combined experimental and theoretical analysis.
- Neutral versus charged species in enzyme catalysis. Classical and free energy barriers for oxygen atom transfer from C4a-hydroperoxyflavin to dimethyl sulfide.
- Effect of geminal substitution on the strain energy of dioxiranes. Origin of the low ring strain of dimethyldioxirane.
- The effect of substitutents on the strain energies of small ring compounds.
- Electronic Factors Influencing the Decarboxylation of beta-Keto Acids. A Model Enzyme Study.
- The Energetics of Valence Isomerization in the Norbornadiene-Quadricyclane System.
Schools
Columbia Univ Coll Of Physicians and Surgeons
Doctors Specialties
- General Surgery
Accepted Insurances
Awards
- Fellow (FACS)
Drug Facts
| NPI NUMBER | 1588754790 | |
| NPPES Provider LastName | BACH | |
| NPPES Provider FirstName | ROBERT | |
| NPPES Provider ZIPCode | 044016616 | |
| NPPES Provider State | ME | |
| Specialty Description | General Practice | |
| Total Claim Count | 28.0 | |
| Distinct Opioid Count | 0.0 | |
| Opioid Claim Count | 0.0 | |
| Percent Opioid Claims | 0.0 |
Helpful Reviews
Medicare Facts
| National Provider Identifier [NPI] | 1588754790 |
| Last Name Of The Provider | BACH |
| First Name Of The Provider | ROBERT |
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